You want two pages per sheet, right? The "2 pages per sheet" setting in Page Setup allows you to do that. What Word shows you, unless you opt to show two pages, is a single page (which will print on half the sheet). You add a page number to that page. If
you want the page numbers on the outside, you must enable "Different Odd and Even" for the header and footer and then place the page numbers as desired in the Odd Page Header/Footer and Even Page Header/Footer. You will see only one page at a time, but when
you print, you will get two pages on one sheet.
If you're trying to create a printed booklet, then you should use "Book fold" instead of "2 pages per sheet." What you'll see in Word will be exactly the same, but when you print, the pages will be paired so that they can be folded into a booklet. But 100
pages (25 sheets) or so is about the absolute limit for a folded booklet. Anything longer than that is not suitable for folding because trimming makes the margins too uneven.
FWIW, there is no Daiya in this conversation, but here's the relevant dialog in Word 2013:
The dialog is essentially the same in all versons of Word. The easiest way to access it is by double-clicking at the top of the horizontal ruler, but you can also get there via the dialog launcher in the
Page Setup group on the Page Layout tab or via
Page Layout | Page Setup | Margins | Custom Margins....