I use my Visa debit card all the time OP. As long as it is an active debit card with your bank (open account, good expiration date on the card, ect) then yes you can use it to purchase items and memberships for Xbox LIVE. My Visa Debit card is currently
my only linked payment method and it has never failed me.
@WPAK - Option 6 on that link is talking about the Windows Phone Store, not XBL Store, just a heads up :)
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