I recently purchased Civ 5 on PC via Steam. Shouldn't I somehow be able to not only get the Steam achievements but also XBL 360 points when playing it on my PC? How do I set this up?
Do you mean get the points twice or just get the PC version of the game showing on your games list here?
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It has to be a GFWL game, that is also Live enabled. Batman AA is one and the game's Live registration is part of the initial setup. Not all GFWL games on STEAM are Live enabled, but.
A list of Games for Windows Live titles (Windows PC games that support achievements like Xbox) can be found here