Hi, Rabelani,
What version of Windows and Internet Explorer are you using?
How to use Group policy to configure home page settings
http://www.grouppolicy.biz/2010/02/how-to-use-group-policy-to-configure-home-page-settings-part-1/
Multiple IE home page can be set using Group Policy Preferences under User Configuration > Preferences > Control Panel Settings > Internet Settings .... then create a new IE7 or IE8 Internet Setting and configure the home pages from there...
OR
If you are using IE8 you can also use the native group policy settings "Disable changing secondary home page settings" and "Disable changing home page settings" to configure a users home page.