I assume that you're using Adobe Acrobat Reader DC to view pdf files.
Open Acrobat Reader (with or without a file) and click Edit > Preferences (or press CTRL+K).
Select "General" in the list of Categories if it isn't already selected.
UNcheck "Open documents as new tabs in the same window (requires restart)"
Click OK
Close Acrobat Reader
Open your two documents, click on the Title Bar in one window and drag to the left side of your screen then click on the Title Bar in the other window and drag to the right side of your screen.
----- LemP Volunteer Moderator MS MVP (Windows Desktop Experience) 2006-2009 Microsoft Community Contributor (MCC) 2011-2012
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