I had this same problem this past April-June 2020, and posted comment on it in June here:
https://answers.microsoft.com/en-us/windows/forum/all/localservicenonetworkfirewall-does-microsoft-ever/97878d20-441b-4ea0-87bb-004ef399f9d5
This time LocalServiceNoNetworkFirewall not only seems to fire up when trying to open a PDF file, but seems to block my ability to open any new app window for minutes at a time.
Until about a week ago, the problem went away soon after my June post, and I was happy that it somehow went away, but now it is more frustrating than ever.
I see you mention AVG, which is something I wondered about as well, since AVG is also doing firewalling, so I wonder if Windows Defender and AVG are somehow conflicting?
Do others that are seeing this problem run AVG?