Hi Tibbur,
I'm Rodrigo, Independent Advisor and I will help you.
There isn't a default app to open .css on Windows. If you want to reset it to no default app you will need to change it in registry editor.
To open the Registry Editor: Open The Start Menu, type regedit and press Enter.
Go to the path below (you can copy and paste on the address bar)
HKEY_CURRENT_USER\SOFTWARE\Microsoft\Windows\CurrentVersion\Explorer\FileExts.css
Expand the folders under .css on the navigation panel and delete "User Choice", it will reset the file association to no program.