Hello how are you?
Welcome to the Microsoft Community!
My name is Marcelo C., I am an independent consultant, I am here to help you in the best possible way.
It is possible to play but only games that you have purchased online (at microsoft) and the titles that are supported to play anywhere.
To access the list of games available for this you can access the website:
https://www.xbox.com/en-us/games/xbox-play-anyw...
or go to microsoft store and access games.
I hope the information above helps. Please let me know how it goes.
Have a nice day and stay safe.
Marcelo de C.