It doesn't work for me either, even though I'm an admin on the system.
I got around it by opening the System page in Control Panel (Win+X -> Y), going to "Advanced system settings", then clicking "Environment Variables". That properly launches the edit window and it works.
By the way, when was the graphical list view of the Path variable introduced? I remember having to manually edit the string, but now a window shows up that lists each path entry in rows. Was that added in Win10?
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