Hello Dee,
If I understand correctly, you are not able to add your second Outlook account to your first Outlook account on the Outlook web.
If you were trying to add an existing Outlook account to another Outlook account as an alias, it is not possible to add an existing Microsoft account as an alias to another Microsoft account. Kindly read this article to understand better: https://support.microsoft.com/en-us/office/add-or-remove-an-email-alias-in-outlook-com-459b1989-356d-40fa-a689-8f285b13f1f2
You can only add multiple accounts on the Outlook desktop app. With this, you will be able to access every folder of your added accounts separately on the new Outlook desktop app.
Take the following steps install the new Outlook app:
1. Type Microsoft store on your windows search bar to install the new Outlook.
2. Search for Outlook for Windows by typing it on the search bar.
3. Click on the app from the search results.
4. Click on Install button to download and install the Outlook app.
Once it is downloaded, register your first outlook account on it.
Take the following steps to add accounts on the new Outlook app:
1. Open the new Outlook app.
2. Click on Settings (gear button from top-right).
3. Click on Accounts.
4. Click on + Add account. Enter your email address and follow the on-screen instructions to add your account.
Kindly let me know if you need further clarification on this.
Regards,
Rita.