Thanks for your help - it put me on the right track.
Here are the steps I used to fix the problem:
1 Shut down Outlook
2 Opened Mail applet
3 Opened E-Mail Accounts, then Data Files
4 Removed offending entry (removes the pointer, not the actual file)
5 Restarted the Mail applet
6 Opened E-Mail Accounts, then Data Files
7 Added entry and pointed to proper file and location
8 Closed the Mail applet
9 Restarted Outlook
Everything back to normal
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