I would like to use an official version of Office365 with company login, but still be connected to my personal OneDrive folders in my windows explorer file structure.
Is this possible?
Yes it's doable, please note that personal OneDrive and OneDrive for Business are different services,
the login sites, login account types are different.
However, they can be managed by the same OneDrive sync client, just add the accounts you want and you will be able to find them in Windows Explore, both personal OneDrive and OneDrive for Business.
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