Same behaviour with antivirus disabled and after resetting timezone.
I've replied to your PM with a log. The entry that stands out to me from the log is: HttpHeader:X-Ms-diagnostics 28042;source="REDACTED_HOST.EXAMPLE.ORG";reason="Too many outstanding requests for a single user.
This seems a strange message - I haven't tried to sign in from any of my devices for the last 48 hours.
In context (hostnames redacted):
POST https://redacted_host.example.org/ucwa/v1/applications
Request Id: <Removed for privacy>
HttpHeader:Cache-Control private
HttpHeader:client-request-id 5898d30d-79c4-4bcb-bf08-5450d64ea362, eac43b64-86cd-4fb2-bf50-684432c09742
HttpHeader:Content-Length 27
HttpHeader:Content-Type text/html
HttpHeader:Date Sun, 03 Feb 2019 17:43:54 GMT
HttpHeader:StatusCode 503
HttpHeader:Strict-Transport-Security max-age=31536000; includeSubDomains
HttpHeader:User-Agent SfBForMac/16.24.191.0000 (Mac OSX 10.13.6)
HttpHeader:Via 1.1 REDACTED_HOST.EXAMPLE.ORG RtcExt
HttpHeader:X-MS-Correlation-Id 2147483796, 2147504597
HttpHeader:X-Ms-diagnostics 28042;source="REDACTED_HOST.EXAMPLE.ORG";reason="Too many outstanding requests for a single user."
HttpHeader:X-MS-Server-Fqdn REDACTED_HOST.EXAMPLE.ORG
The service is unavailable.
</ReceivedResponse>
I believe the organisation uses the online service. I haven't been able to find anyone else with a mac to confirm if it works.