Hi Mark,
Here is a wiki introduces the Microsoft Online Services Sign-In Assistant (MOS SIA), for your reference:
https://community.office365.com/en-us/w/sso/534
Regarding your situation, would you provide us with some more detailed information about “When I logged in My and open the one drive site it asks me password”, do you encounter this in the desktop OneDrive client or Office 365 portal from browser?
Could you also provide a screenshot about this for our reference?
To insert a screenshot, please click on Use rich formatting and select the
Insert Image icon.
*Note: On June 17th, this community is migrating to Microsoft Community at
http://answers.microsoft.com. If you need further assistance, please post a new question to the Office 365 for business forum beginning June 18th Pacific Time. Thank you for your understanding.
Regards,
Allan